Optical spectrum based measurement of flotation slurry contents   总被引：1，自引：1，他引：0  

Olli Haavisto  Jani Kaartinen  Heikki Hytyniemi 《International Journal of Mineral Processing》2008,88(3-4):80-88

Monitoring and control of a flotation circuit is mainly based on the information gained by assaying the process slurry lines. In flotation plants, usually an X-ray fluorescence analyzer is used to obtain the on-line assays. This article introduces the visual and near-infrared reflectance spectroscopic analysis of the process slurries as a supplementary method which complements the on-line assay information available from an X-ray fluorescence analyzer. It is shown that the spectral information can be used to accurately predict the element contents in the slurry in between successive XRF analyses. Since the spectral measurements can be taken with high frequency as opposed to the sparse X-ray fluorescence analysis, a practically continuous on-line estimate of the slurry contents is reached. These estimates can be used in the plant control to improve the overall performance of the circuits and to yield also economical savings. Additionally, the frequent monitoring of the grades can provide means to eliminate rapid disturbances in the circuits, thus improving the stability of the process.  相似文献   

Exploiting the dual functions of polymer depressants in fine particle flotation   总被引：1，自引：0，他引：1  

Qi Liu  David Wannas  Yongjun Peng 《International Journal of Mineral Processing》2006,80(2-4):244-254

Fine hydrophilic particles are known to be entrained with water in flotation of many ores. Flocculation of the hydrophilic particles by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxyapatite and sphalerite, as well as on a relatively coarse quartz sample (− 75 + 38 μm). Dodecylamine was used as a collector for quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, cornstarch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700,000 and 80,000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 mL flotation column. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of synthetic mixtures of the − 75 + 38 μm quartz and fine (reagent grade) iron oxide or hydroxyapatite, polymer depressants that caused flocculation performed better than those that did not cause flocculation.  相似文献   

Modified column flotation of adsorbing iron hydroxide colloidal precipitates     

F. Capponi  M. SartoriM.L. Souza  J. Rubio 《International Journal of Mineral Processing》2006

A promising technique for the removal of heavy metal ions from wastewater streams involved firstly the ions adsorption on a colloidal precipitate (carrier) and then the separation of the loaded flocs (coagula) by a modified column flotation. Here, the effluent feed and the carrier (ferric hydroxide) enter smoothly by the top of the column through a special diffuser, in counter current with rising bubbles (100–600 μm diameter) generated by using recycled water, surfactant and air suction through a venturi. High separation values of the column flotation of the carrier precipitates were achieved, despite the high superficial flow rate and the high Fe^+ 3 concentration utilized (> 60 mg L^− 1 Fe). No rupture of colloidal carrier aggregates was observed and a low split was ensured by monitoring the concentrate (floated product) flow rate. Results indicated that best separation was attained by controlling the medium pH (for best heavy metal ion adsorption onto the carrier), followed by sodium oleate, used as “collector” and optimizing operating parameters (conditioning, flow rates, etc.). The column throughput reached 43 m h^− 1 (m³ m^− 2 h^− 1), which is about 4 times the normal capacity of DAF-dissolved air flotation unit, the most used floater in wastewater treatment. Various metals (Cu, Ni, Pb, etc.) and molybdate ions present in synthetic and real effluent were successfully removed based on this colloidal adsorbing flotation principle. The process was also applied in a pilot scale to treat an industrial electroplating wastewater. Most of toxic metals (Cu, Ni and Zn) were reduced from initial concentrations of about of 2 to 10 mg L^− 1, to below 0.5 to 1.0 mg L^− 1, meeting local municipal discharge limits (but Cd ions). It is believed that flotation separation using medium-sized bubbles has great potential as a clean water and wastewater treatment technology.  相似文献   

Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector     

M. Barbaro  R. Herrera Urbina  C. Cozza  D. Fuerstenau  A. Marabini 《International Journal of Mineral Processing》1997,50(4):275-287

A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation.  相似文献   

氯化钠存在下氯化亚锡—罗丹明B—水体系浮选分离铱   总被引：5，自引：1，他引：5  

高云涛  吴立生等 《岩矿测试》2002,21(2):117-119

研究了Ir（Ⅲ）在NaCl存在下SnCl2－罗丹明B－水体系中的浮选行为，在1.0mol/L HCl介质中，Ir（Ⅲ）与Pd,Pt,Rh,Au同时被浮选，Ir（Ⅲ）的浮选率为99.2％，并与常见贱金属离子分离，被浮选分离的Ir可采用原子吸收法测定，结果与火试金分离富集法相符。精密度试验，相对标准偏差（RSD，n＝5）＜3％。  相似文献   

Flotation Separation of Trace Elements from Alkaline-Earth Matrices by Co(III) Hexamethylenedithiocarbamate before ICP-AES Determination     

Vesna Zajkova Paneva  Katarina Cundeva  Trajce Stafilov 《Geostandards and Geoanalytical Research》2007,31(1):51-60

A method for the selective separation of Ag, Cd, Cr, Cu, Ni, Pb and Zn in traces from solutions of calcite (CaCO₃), dolomite (CaMg(CO₃)₂) and gypsum (CaSO₄.2H₂O) before their determination by inductively coupled plasma-atomic emission spectrometry (ICP-AES) is presented. The expected interferences of Ca and Mg on intensities of trace analytes were removed by collecting the elements of interest with cobalt(III) hexamethylenedithiocar-bamate, Co(HMDTC)₃. The flotation of aqueous solutions (1 l) of calcite, dolomite and gypsum was performed at pH 6.0, by 1.5 mg l⁻¹ Co and 0.6 mmol l⁻¹ HMDTC⁻. To minimise the effect of the reaction between Ca/Mg, which restrains the function of the surfactant, careful selection of the most suitable foaming reagent was necessary. The accuracy of the method was established by analysing natural alkaline-earth minerals by the standard addition method as well as using the dolomite reference materials GBW 07114 and GSJ JDo-1. The ICP-AES limits of detection following flotation on different minerals were found to be 0.080 μg g⁻¹ for Cd, 0.105 μg g⁻¹ for Ag, 0.142 μg g⁻¹ for Cu, 0.195 μg g⁻¹ for Cr, 0.212 μg g⁻¹ for Ni, 0.235 μg g⁻¹ for Zn and 0.450 μg g⁻¹ for Pb.  相似文献   

免疫胶体金检测中华鳖抗毒素抗体和嗜水气单胞菌外毒素     

邱德全  何建国  钟英长  江静波 《广东海洋大学学报》1998,(1)

以中华鳖的嗜水气单胞菌纯化其外毒素,用胶体金建立斑点免疫检测方法,测定中华鳖对嗜水气单胸菌外毒素抗体效价。结果表明：该方法有高的特异性,与血清中的其它成分交叉反应小;检测灵敏度达4ng。  相似文献   

福建某低品位钼矿选矿试验研究     

童友焜 《福建地质》2014,(1):62-69

针对福建某低品位钼矿矿石性质,确定了粗磨粗选、粗精矿再磨精选的浮选方案。采用该浮选方案及合理的选别条件,对含钼为0.08%的钼原矿选别,获得钼精矿品位52.45%、钼精矿产率为0.14%、钼回收率90.19%的良好指标。  相似文献   

甘肃某石英脉型难选金矿石选矿试验研究     

刘国英  刘江  祖述宇  郭文军  罗娜 《地质找矿论丛》2011,26(3):354-358

甘肃某金矿为含金石英脉型硫化矿石,金的嵌布粗细不均匀分布,70％以上集中在粗粒级中,而细粒级金则主要被黄铁矿和脉石矿物包裹,难以解离,导致尾矿中金品位难以降低,该矿石属于较难选矿石.试验研究初步对该矿石采用“重选十浮选”的工艺流程,选别效果不好;而采用把矿石磨细再经过一粗三扫的单一浮选工艺流程,在磨矿细度为-0.074...  相似文献   

天然胶体的水环境行为     

王沛芳  包天力  胡斌  钱进 《湖泊科学》2021,33(1):28-48

胶体是一种分散相粒子具有特定粒径(通常为1 nm~1μm)的混合物,天然水体中的胶体通常是指水环境中普遍存在,而又符合“胶体”形态定义的物质的总和.因为具有特殊的表面性质以及独特的水动力学特点,天然水体中的胶体被认为是一种重要的污染物载体,尤其在促进重金属类的污染物迁移以及性质转化的过程中具有重要作用.本文归纳总结了水环境研究领域中胶体概念的提出与发展,讨论了现有研究中对胶体的定义与理解,比较了当前几种主要的胶体提取手段的特点.同时,针对胶体在水环境中的环境行为,详细归纳了河湖水体中胶体的物质组成、特征以及相应的检测手段,重点总结了胶体在水环境中对污染物的结合作用、胶体污染物的生物效应、胶体自身的团聚规律以及胶体对污染物迁移的影响机制.本文提出了胶体在水环境中复杂的组成成分与动态变化在胶体研究中的重要性,并对进一步揭示胶体环境效应的研究思路以及方法手段进行了展望.  相似文献